Kew, B orcid.org/0000-0003-4550-6999, Holmes, M orcid.org/0000-0002-6819-1048, Stieger, M orcid.org/0000-0002-8736-6026 et al. (1 more author) (2021) Oral tribology, adsorption and rheology of alternative food proteins. Food Hydrocolloids, 116. 106636. ISSN 0268-005X
Abstract
Mechanistic knowledge using tribology and adsorption may help to screen various proteins with better lubrication; aiding the fast tracking of new ingredient formulations for use in low-fat/high protein food development. The aim of this study was to compare the lubrication, adsorption and physicochemical properties of alternative proteins (pea, potato, lupin and insect proteins) with whey protein isolate (WPI) as the control. Soluble fractions (1-10 wt%) of pea protein concentrate (PPCsol), insect protein concentrate (IPCsol), potato protein isolate (PoPIsol) and lupin protein isolate (LPIsol) were chosen as the alternative proteins. All proteins were negatively-charged at neutral pH and showed various degrees of aggregation (hydrodynamic diameters ranging from 25 nm for PoPIsol to 244 nm for PPCsol). The boundary friction coefficient (μ) at 5 wt% protein followed the trend as PPCsol> LPIsol> IPCsol> PoPIsol> WPIsol, highlighting excellent lubrication performances of PoPIsol, IPCsol and WPIsol. At higher protein concentrations (10 wt%), μ significantly increased for LPIsol, PoPIsol and IPCsol, while decreasing for WPIsol. Quartz crystal microbalance with dissipation monitoring (QCM-D) results revealed formation of rigid elastic films on hydrophobic surfaces by PoPIsol and WPIsol giving rise to low μ while more viscous films by PPCsol led to high μ. PPCsol had the highest hydrated mass (11.0 mg m-2) as compared to WPIsol (8.0 mg m-2) with lower values reported for other proteins (5.0-5.4 mg m-2). Strong correlations existed between μ scaled to viscosity, size and hydrated mass and viscoelasticity of films in alternative proteins, validating the surface-linked phenomena in frictional response.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2021 Elsevier Ltd. All rights reserved. This is an author produced version of an article published in Food Hydrocolloids. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | Friction; plant protein; QCM-D; viscosity; sustainability; insect protein |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Food Science and Nutrition (Leeds) > FSN Colloids and Food Processing (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 03 Feb 2021 12:26 |
Last Modified: | 08 Jan 2025 14:31 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.foodhyd.2021.106636 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:170645 |