Bonnet, L.G. and Douthwaite, R.E. (2003) Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction. Organometallics, 22 (21). pp. 4187-4189. ISSN 0276-7333
Abstract
Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)−imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Dates: |
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| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 12 Mar 2009 11:24 |
| Last Modified: | 12 Mar 2009 11:24 |
| Published Version: | http://dx.doi.org/10.1021/om034050z |
| Status: | Published |
| Publisher: | Johns Hopkins University Press |
| Identification Number: | 10.1021/om034050z |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:7135 |
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