Utilizing soil centrifugation for accurate estimates of carbon dioxide removal via enhanced rock weathering

Enhanced rock weathering (ERW) is a promising CO<inf>2</inf> removal (CDR) strategy that aims to accelerate the natural process of silicate weathering to increase soil pore water alkalinity and sequester CO<inf>2</inf>. However, the measurement, reporting, and verification (MRV) of ERW remains challenging due to existing limitations of aqueous-phase sampling methodologies, such as passive and tension lysimeters, which may not fully capture weathering fluxes across varying soil moisture conditions. This study assesses the potential of a centrifugation-based pore water extraction method to improve the accuracy and reliability of ERW measurements. Using a forest ERW trial in Wales, UK, we compared the chemistry of soil pore waters obtained via lysimeters and centrifugation from feedstock-amended and control plots. The centrifugation method detected elevated total alkalinity and Ca concentrations in soil pore waters from feedstock-amended soils, whereas the effect of feedstock amendment was not detectable in pore waters extracted with lysimeters. The high tensions applied during centrifugation likely capture weathering products dissolved in meso- and micropore water, which lysimeters cannot extract. These findings suggest that centrifugation provides a scalable, low-cost approach for ERW monitoring, with implications for improving existing MRV protocols.