McEllin, Alice Jane, Goult, Christopher A., Whitwood, Adrian C. et al. (2 more authors) (2023) On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand. Dalton Transactions. D2DT04114F. pp. 872-876. ISSN: 1477-9226
Abstract
The C^N^C ligand 2,6-bis(2,3-dialkoxyphenyl)pyridine forms dimercury and orthopalladated complexes, both of which may be transmetallated to gold(iii) complexes; the gold complexes may also be formed directly in a Rh(iii)-catalysed process, hence it is possible to circumvent the use of organomercury intermediates in the synthesis of this important class of compound.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | Funding Information: We thank the University of York for funding (AJM & CAG). JML is supported by a Royal Society Industry Fellowship. Publisher Copyright: © 2023 The Royal Society of Chemistry. |
| Dates: |
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| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Funding Information: | Funder Grant number THE ROYAL SOCIETY INF\R1\221057 |
| Depositing User: | Pure (York) |
| Date Deposited: | 31 Jan 2023 15:20 |
| Last Modified: | 20 Sep 2025 01:57 |
| Published Version: | https://doi.org/10.1039/d2dt04114f |
| Status: | Published |
| Refereed: | Yes |
| Identification Number: | 10.1039/d2dt04114f |
| Related URLs: | |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:195909 |

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