Veazey, R.A. orcid.org/0000-0001-5827-3771, Gandy, A.S. orcid.org/0000-0003-3692-6211, Sinclair, D.C. orcid.org/0000-0002-8031-7678 et al. (1 more author) (2020) Finite element modeling of resistive surface layers by micro‐contact impedance spectroscopy. Journal of the American Ceramic Society, 103 (4). pp. 2702-2714. ISSN 0002-7820
Abstract
Micro‐contact impedance spectroscopy (MCIS) is potentially a powerful tool for the exploration of resistive surface layers on top of a conductive bulk or substrate material. MCIS employs micro‐contacts in contrast to conventional IS where macroscopic electrodes are used. To extract the conductivity of each region accurately using MCIS requires the data to be corrected for geometry. Using finite element modeling on a system where the resistivity of the surface layer is at least a factor of ten greater than the bulk/substrate, we show how current flows through the two layers using two typical micro‐contact configurations. This allows us to establish if and what is the most accurate and reliable method for extracting conductivity values for both regions. For a top circular micro‐contact and a full bottom counter electrode, the surface layer conductivity (σs) can be accurately extracted using a spreading resistance equation if the thickness is ~10 times the micro‐contact radius; however, bulk conductivity (σb) values can not be accurately determined. If the contact radius is 10 times the thickness of the resistive surface, a geometrical factor using the micro‐contact area provides accurate σs values. In this case, a spreading resistance equation also provides a good approximation for σb. For two top circular micro‐contacts on thin resistive surface layers, the MCIS response from the surface layer is independent of the contact separation; however, the bulk response is dependent on the contact separation and at small separations contact interference occurs. As a consequence, there is not a single ideal experimental setup that works; to obtain accurate σs and σb values the micro‐contact radius, surface layer thickness and the contact separation must all be considered together. Here we provide scenarios where accurate σs and σb values can be obtained that highlight the importance of experimental design and where appropriate equations can be employed for thin and thick resistive surface layers.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2019 The Authors. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited (http://creativecommons.org/licenses/by/4.0/). |
Keywords: | electroceramics; electrodes; finite element analysis; impedance spectroscopy; spreading resistance |
Dates: |
|
Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number Engineering and Physical Science Research Council EP/L017563/1; EP/L015390/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 10 Mar 2020 12:17 |
Last Modified: | 10 Mar 2020 12:17 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1111/jace.16981 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:156950 |
Download
Filename: Veazey_et_al-2020-Journal_of_the_American_Ceramic_Society.pdf
Licence: CC-BY 4.0