Kirchhecker, Sarah orcid.org/0000-0003-0470-8228 and Bruce, Duncan Watson orcid.org/0000-0002-1365-2222 (2019) Chiral Ionic Liquid Crystals based on Thiourea. NEW JOURNAL OF CHEMISTRY. pp. 2053-2056. ISSN: 1144-0546
Abstract
Chiral ionic liquid crystals based on the S-methyl-N,N'-α-methylarylthiouronium cation have been prepared and studied. Most salts, interestingly including an example with the bistriflimide anion, display a SmA* phase with anion-dependent transition temperatures. The salts, which are able to distinguish enantiomers of chiral anions via formation of diastereomeric adducts, may find application as chiral reaction media.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. |
| Dates: |
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| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Depositing User: | Pure (York) |
| Date Deposited: | 13 Jun 2019 11:00 |
| Last Modified: | 20 Sep 2025 00:56 |
| Published Version: | https://doi.org/10.1039/C8NJ06434B |
| Status: | Published |
| Refereed: | Yes |
| Identification Number: | 10.1039/C8NJ06434B |
| Related URLs: | |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:147283 |

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