Allen, B.D.W., Lakeland, C.P. and Harrity, J.P.A. (2017) Utilizing Palladium-Stabilized Zwitterions for the Construction of N-Heterocycles. Chemistry - A European Journal , 23 (56). pp. 13830-13857. ISSN 0947-6539
Abstract
Pd catalysis provides a convenient method for the generation of zwitterionic intermediates that offer significant opportunities for the synthesis of functionalized heterocycles. The combination of electrophilic π-allyl Pd fragments and C-, N- and O-centered nucleophiles allows these intermediates to react with readily available substrates to furnish a range of high value products with control of chemo-, regio- and stereo-selectivity.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | This is the peer reviewed version of the following article: B. D. W. Allen, C. P. Lakeland, J. P. A. Harrity, Chem. Eur. J. 2017, 23, 13830, which has been published in final form at https://doi.org/10.1002/chem.201702486. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
Keywords: | catalysis; cycloaddition; enantioselective; heterocycles; palladium |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 31 Oct 2017 13:15 |
Last Modified: | 21 Aug 2018 00:38 |
Published Version: | https://doi.org/10.1002/chem.201702486 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1002/chem.201702486 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:123238 |