Modeling the time evolution of the structure factor during polymeric spinodal decomposition using dynamic mode decomposition

The development of the microstructure during polymeric spinodal decomposition can be monitored in real time using small-angle scattering. Information about the microstructure can be deduced from measurements of the structure factor—a quantity directly proportional to the scattered intensity. While the time evolution of the structure factor can be measured relatively easily, modeling it has proved to be much more difficult. We believe the latter could be impeding our ability to control spinodal decomposition. Using synthetic data corresponding to two different polymer blends, we investigate the use of dynamic mode decomposition to model the time evolution of the structure factor during polymeric spinodal decomposition. Based on the accuracy and range of the predictions we obtained using dynamic mode decomposition, we believe our results are promising for the use of dynamic mode decomposition in an experimental setting, which could improve our ability to control spinodal decomposition in automated experiments.