Hayatgheib, Y., Owen, J., Bhamji, R. et al. (8 more authors) (2024) Effect of brine salinity on the partitioning, distribution and corrosion inhibition performance of a quaternary amine corrosion inhibitor. Journal of Pipeline Science and Engineering, 4 (3). 100181. ISSN 2667-1433
Abstract
Surfactant corrosion inhibition performance in water–oil environments is influenced by complex relationships between their physical properties, solution chemistry and interfacial characteristics. The existence of polar heads/nonpolar tails influences both the preferential distribution of the surfactant between the two media as well as the phase in which micellisation occurs. Both phenomena affect the efficiency of the surfactant inhibitor and its adsorption at the metal-solution interface. To demonstrate the complexity of such interactions, the effect of brine salinity on the critical micelle concentration (CMC) and partitioning/distribution behaviour of a quaternary amine corrosion inhibitor (alkyldimethylbenzylhexadecylammonium chloride, or BAC-C₁₆) in a brine and toluene system (at 1:1 ratio) was explored. All experiments were conducted at 50 °C and pH4 over varying salinities (0.1, 1 and 10 wt%) of NaCl brine. Both CMC and partitioning characteristics of BAC-C₁₆ are significantly affected by aqueous phase salinity, with an inversion of the partitioning response observed between concentrations of 0.1 and 1 wt% NaCl. The effect of BAC-C₁₆ partitioning/distribution behaviour on corrosion inhibitor performance was examined using rotating cylinder electrode experiments. The results illustrate that in order to establish the true corrosion inhibition behaviour, consideration of the chemical distribution characteristics is crucial.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2024 The Authors. Publishing Services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
Keywords: | CO₂ corrosion; Partitioning; Corrosion inhibitors; Water-oil environments; Salinity; Micellisation |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) > Institute of Functional Surfaces (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 15 Jul 2024 15:12 |
Last Modified: | 15 Jul 2024 15:12 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.jpse.2024.100181 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:214309 |