Garrote Cañas, A.M. orcid.org/0000-0001-8848-3630, Yong, X. orcid.org/0000-0003-1674-754X, Alenezi, M.S. et al. (2 more authors) (Cover date: March 2024) Phenanthrolines decorated with branched lipophilic chains and their yellow emitting heteroleptic iridium(III) complexes: Synthesis, photophysical and acidochromic behaviour, and computational analysis. Dyes and Pigments, 222. 111844. ISSN 0143-7208
Abstract
To improve the solubility and to manipulate the optical properties of phenanthroline-based materials, a series of compounds with branched lipophilic chains Phen1-4 was prepared in three steps with the yield of 22–81%. In addition, a related phenanthroline-based bidental compound Phen5 was synthesised with blocked N sites on imidazolyl units to influence π-π* and n-π* transitions and to increase FPL. The optical properties were analysed by UV–vis absorption and fluorescence spectroscopy, showing a strong emission at 427–437 nm and improved FPL for the series (20–68%). Furthermore, Phen2-4 and bidental Phen5 exhibited a clear acidochromic behaviour with a dramatic shift in absorption spectra of ca. 30 nm achieved after the addition of 1 eq. and 2 eq. of an acid (TFA), respectively. Likewise, all compounds showed a loss of fluorescence under acidic conditions. Next, to test the complexation ability of these ligands, the heteroleptic iridium(III) complexes Ir1-4 were prepared in excellent yields (86–98%), along with the binuclear complex Ir5. Their optical properties revealed strong yellow emission centered at 539–571 nm with FPL of up to 7%; additionally, all complexes exhibited large Stokes shifts (220–290 nm).
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by- nc-nd/4.0/). |
Keywords: | Phenanthroline, Photoluminescence, Computational modelling, Heteroleptic iridium(III) complexes, Acidochromism, Lipophilic chains |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Arts, Humanities and Cultures (Leeds) > School of Design (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 08 Dec 2023 10:38 |
Last Modified: | 08 Jan 2024 16:38 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.dyepig.2023.111844 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:206382 |