Hindle, A, Baj, K, Iggo, JA et al. (4 more authors) (2023) Modular Synthesis of Bicyclic Twisted Amides and Anilines. Chemical Communications. ISSN 1359-7345
Abstract
Bridged amides and anilines display interesting properties owing to perturbation of conjugation of the nitrogen lone-pair with the adjacent π-system. A convergent approach to diazabicyclic scaffolds which contain either twisted amides or anilines is described, based on the photocatalysed hydroamination of cyclic enecarbamates and subsequent cyclisation. The modular nature of the synthesis allows for variation of the degree of ‘twist’ and hence the properties of the amides and anilines.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2023. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Funding Information: | Funder Grant number EPSRC (Engineering and Physical Sciences Research Council) EP/K503526/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 24 Apr 2023 12:01 |
Last Modified: | 24 Apr 2023 12:01 |
Status: | Published online |
Publisher: | Royal Society of Chemistry (RSC) |
Identification Number: | 10.1039/d3cc01470c |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:198448 |