Han, Z, Hu, X, He, T orcid.org/0000-0001-8975-8667 et al. (4 more authors) (2022) Early Jurassic long-term oceanic sulfur-cycle perturbations in the Tibetan Himalaya. Earth and Planetary Science Letters, 578. 117261. ISSN 0012-821X
Abstract
The Early Jurassic is an important interval characterized by several global carbon-isotope (δ13C) perturbations. Although the δ13C records are becoming better documented during this time interval, we have a relatively poor understanding of the associated long-term environmental and climatic changes. In order to decipher these events, we here present new stable sulfur-isotope data of carbonate-associated sulfate (δ34SCAS) for the Sinemurian–Pliensbachian interval from the Wölong section in the Tibetan Himalaya that was located palaeogeographically in the southern hemisphere. An overall positive shift in δ34SCAS coincides with the negative δ13C excursion around the Sinemurian–Pliensbachian boundary, suggesting an increased 34S-depleted pyrite burial rate. The ensuing overarching negative δ34SCAS shift coincides with the upper Pliensbachian positive δ13C excursion. The initial falling limb of the δ34SCAS shift suggests a transient δ34S-depleted sulfate input, but this trend was soon reversed to become positive, likely caused by a persistently enhanced 32S-rich pyrite burial flux in the latest Pliensbachian.
Modeling results show that maximum oceanic sulfate concentration likely decreased during the Sinemurian–Toarcian interval, probably due to large-scale evaporite deposition in the western Tethys and proto-Atlantic and enhanced pyrite burial in a number of marine settings. The concentration of seawater sulfate could have been high enough to maintain a homogeneous sulfur-isotope ocean in the late Sinemurian, but its persistent decrease may have initiated a spatially heterogeneous ocean after the Pliensbachian: an oceanic geochemical state that was amplified during the Toarcian Oceanic Anoxic Event.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2021 Elsevier B.V. All rights reserved. This is an author produced version of an article published in Earth and Planetary Science Letters. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | carbonate platform; Early Jurassic; seawater sulfate concentrations; southern hemisphere; sulfur-isotope perturbations; Tibetan Himalaya |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Earth and Environment (Leeds) > Earth Surface Science Institute (ESSI) (Leeds) |
Funding Information: | Funder Grant number NERC (Natural Environment Research Council) NE/N018559/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 29 Oct 2021 10:36 |
Last Modified: | 20 Nov 2022 01:13 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.epsl.2021.117261 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:179545 |
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