Lazareva, A, Owen, J orcid.org/0000-0003-0778-0858, Vargas, S et al. (2 more authors) (2021) Investigation of the evolution of an iron carbonate layer and its effect on localized corrosion of X65 carbon steel in CO2 corrosion environments. Corrosion Science, 192. 109849. ISSN 0010-938X
Abstract
The general and localized corrosion of X65 carbon steel in CO2-saturated environments conducive to iron carbonate (FeCO3) formation has been studied using electrochemical measurements, together with post-test surface analysis. This research offers new insights into the evolution of FeCO3 layer and its link to the subsequent initiation and propagation of localized corrosion. We identify crevice-like regions forming at boundaries/edges of the FeCO3 crystals, which constitute the crystalline layer, where small cavities filled with electrolyte are restricted between developing crystals. It is apparent that such crevice-like features act as precursors to the localized/pitting corrosion on carbon steel over longer durations.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2021 Elsevier Ltd. All rights reserved. This is an author produced version of an article published in Corrosion Science. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | A. carbon steel; A. mild steel; B. SEM; B. XRD; C. crevice corrosion; C. pitting corrosion |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) > Institute of Functional Surfaces (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 14 Oct 2021 10:39 |
Last Modified: | 15 Sep 2022 00:14 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.corsci.2021.109849 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:179116 |
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Filename: Final manuscript Iron carbonate evolution and localised corosion.pdf
Licence: CC-BY-NC-ND 4.0