Shamsa, A, Barmatov, E, Hughes, TL et al. (3 more authors) (2022) Hydrolysis of imidazoline based corrosion inhibitor and effects on inhibition performance of X65 steel in CO2 saturated brine. Journal of Petroleum Science and Engineering, 208 (Part B). 109235. ISSN 0920-4105
Abstract
The molecular characteristics of a TOFA/DETA based imidazoline inhibitor were evaluated by analysing the inhibitor protonation profile, the CMC and micelle size and the rate of acid-catalysed hydrolysis of the inhibitor to improve understanding of the corrosion inhibition performance of the main imidazoline component and its hydrolysis products. The ability of the TOFA/DETA imidazoline based corrosion inhibitor and its products of hydrolysis in retarding both uniform and localized corrosion were assessed and compared on wet-ground X65 carbon steel at 80 °C in CO2 saturated 3 wt % NaCl brines. The findings indicate that the imidazoline based inhibitor forms micellar solutions, with a characteristic micelle size of 18 ± 9 nm at the CMC (10 ± 1 ppm) in CO2 saturated 3 wt % NaCl brines, and that under such conditions (pH~4.1), the inhibitor is fully protonated which increases inhibitor solubility/dispersibility and enhances molecular adsorption of the positively charged imidazoline on the metal surface thereby improving inhibition performance. Hydrolysis of the imidazoline and amido-amine is acid-catalysed and the consumption of imidazoline follows a pseudo-first-order reaction mechanism with an activation energy of 72.0 ± 2.9 kJ mol-1. The study concludes that the pre-aged inhibitor has different effects on uniform and localized corrosion behavior of X65 carbon steel.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2021 Elsevier B.V. All rights reserved. This is an author produced version of an article published in Journal of Petroleum Science and Engineering. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | CO2 corrosion; Hydrolysis; Imidazoline inhibitor; Localized corrosion |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) > Institute of Functional Surfaces (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 24 Sep 2021 15:30 |
Last Modified: | 12 Jul 2022 13:03 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.petrol.2021.109235 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:178377 |