Townrow, Oliver P.E., Chung, Cheuk, Macgregor, Stuart A. et al. (2 more authors) (2020) A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes. Journal of the American Chemical Society. pp. 18330-18335. ISSN 1520-5126
Abstract
We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2020, The Author(s). |
Dates: |
|
Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Funding Information: | Funder Grant number EPSRC EP/M024210/2 |
Depositing User: | Pure (York) |
Date Deposited: | 15 Oct 2020 09:10 |
Last Modified: | 16 Dec 2024 00:14 |
Published Version: | https://doi.org/10.1021/jacs.0c09742 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1021/jacs.0c09742 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:166738 |