Townrow, Oliver P.E., Chung, Cheuk, Macgregor, Stuart A. et al. (2 more authors) (2020) A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes. Journal of the American Chemical Society. pp. 18330-18335. ISSN: 1520-5126
Abstract
We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
Metadata
| Item Type: | Article |
|---|---|
| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | © 2020, The Author(s). |
| Dates: |
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| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Funding Information: | Funder Grant number EPSRC EP/M024210/2 |
| Depositing User: | Pure (York) |
| Date Deposited: | 15 Oct 2020 09:10 |
| Last Modified: | 17 Sep 2025 02:11 |
| Published Version: | https://doi.org/10.1021/jacs.0c09742 |
| Status: | Published |
| Refereed: | Yes |
| Identification Number: | 10.1021/jacs.0c09742 |
| Related URLs: | |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:166738 |

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