Dressel, C., Reppe, T., Poppe, S. et al. (5 more authors) (2020) Helical networks of π‐conjugated rods – a robust design concept for bicontinuous cubic liquid crystalline phases with Ia3d and chiral I23 lattice. Advanced Functional Materials, 30 (45). 2004353. ISSN 1616-301X
Abstract
Bicontinuous cubic liquid crystalline phases of π‐conjugated molecules, representing self‐assembled 3D‐ordered interpenetrating networks with cubic symmetry, are receiving increasing attention due to their capacity for charge transport in all three dimensions and their inherent spontaneous helicity. Herein, a robust general design concept for creating bicontinuous cubic phases is reported. It is based on a nonsymmetric‐substituted π‐conjugated 5,5′‐diphenyl‐2,2′‐bithiophene platform with one end containing three out‐fanning flexible chains and with a range of substituents at the other end (the apex). The cubic phases are stable over broad temperature ranges, often down to ambient temperature, and tolerate a wide range of apex substitution patterns, allowing structural diversity and tailoring of the cubic phase type and application‐relevant properties. With an increasing number and size of apex substituents, a sequence of three different modes of cubic self‐assembly is observed, following an increasing helical twist. Thus, two ranges of the achiral double network Ia 3d phase range can be distinguished, a long pitch and a short pitch, with the chiral triple network I23 cubic phase in the intermediate pitch range. The findings provide a new prospect for the directed design of cubic phase‐forming functional materials based on spontaneously formed helical network liquid crystals with tunable application specific properties.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2020 The Authors. Published by Wiley‐VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, (http://creativecommons.org/licenses/by/4.0/) which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
Keywords: | bicontinuous cubic phases; chirality; helical superstructures; liquid crystals; mirror symmetry breaking; self‐assembly; supramolecular networks |
Dates: |
|
Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/P002250/1 ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/T003294/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 25 Aug 2020 10:28 |
Last Modified: | 25 Jan 2022 09:30 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1002/adfm.202004353 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:164689 |