Greatorex, S, Fokin, SV orcid.org/0000-0002-1231-1282, Kulmaczewski, R orcid.org/0000-0002-3855-4530 et al. (7 more authors) (2020) Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn–Teller Distortion. Inorganic Chemistry, 59 (13). pp. 8657-8662. ISSN 0020-1669
Abstract
A series of six-coordinate [Cu(L)L1][BF4]2 (L1 = 2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) complexes are reported. Ferromagnetic coupling between the Cu and L1 ligand spins is enhanced by an L coligand with distal methyl substituents, which is attributed to a sterically induced suppression of its Jahn–Teller distortion.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 American Chemical Society. This is an author produced version of an article published in Inorganic Chemistry. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Funding Information: | Funder Grant number EPSRC (Engineering and Physical Sciences Research Council) EP/K012568/1 Royal Society 2015 RFBR |
Depositing User: | Symplectic Publications |
Date Deposited: | 08 Jun 2020 12:09 |
Last Modified: | 20 Dec 2024 14:27 |
Status: | Published |
Publisher: | American Chemical Society |
Identification Number: | 10.1021/acs.inorgchem.0c01345 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:161623 |