Adams, Gemma M. and Weller, Andrew S. orcid.org/0000-0003-1646-8081 (2018) POP-type ligands:Variable coordination and hemilabile behaviour. COORDINATION CHEMISTRY REVIEWS. pp. 150-172. ISSN 0010-8545
Abstract
Hemilabile ligands – ligands containing two or more potential donors to a metal centre, of which one or more can dissociate – have the ability to provide a transition metal complex with open coordination sites at which reactivity can occur, or stabilise low coordinate intermediates along reaction pathways. POP-type ligands and in particular POP, Xantphos, DBFphos and DPEphos-based ligands contain three possible binding sites: two phosphines and an ether linker, thus have the potential to show κ1-, κ2- or κ3-binding modes. This review summarises the examples where POP-type ligands display hemilabile, or closely related variable coordination, characteristics in either synthesis or catalysis.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2017 The Authors |
Keywords: | Catalysis,DPEphos,Hemilabile ligands,POP ligands,Variable coordination modes,Xantphos |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 03 Jan 2020 12:30 |
Last Modified: | 16 Oct 2024 16:17 |
Published Version: | https://doi.org/10.1016/j.ccr.2017.08.004 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1016/j.ccr.2017.08.004 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:155087 |
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Description: POP-type ligands: Variable coordination and hemilabile behaviour
Licence: CC-BY 2.5