Pellis, Alessandro, Hanson, Polly Ann, Comerford, James William orcid.org/0000-0002-9977-5695 et al. (2 more authors) (2019) Enzymatic synthesis of unsaturated polyesters: functionalization and reversibility of the aza-Michael addition of pendants. Polymer Chemistry. pp. 843-851. ISSN 1759-9962
Abstract
With society's increasing awareness of the problems caused by plastic pollution, the switch to renewable, biodegradable materials is nowadays a must for several producers and consumers. In the present work, the biocatalyzed synthesis of fully renewable polyesters containing lateral vinyl functionalities derived from itaconic, fumaric and maleic acid is presented. Here, an environmentally friendly synthesis was therefore combined with the possibility of obtaining materials that could be functionalized via post-polymerization modifications such as the aza-Michael additions of diethylamine. Moreover, the possibility of reversing the polymer's post-functionalization via a temperature-driven process to obtain free lateral vinyl groups again is also described and analyzed for several polymers based on itaconates and 1,4-butanediol, 1,6-hexanediol and 1,8-octanediol. The collected results set the basis for the development of switchable polymers where pharmaceuticals or other chemicals/polymers can be coupled to the polymeric backbone and released upon changing the material's conditions.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2019. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Funding Information: | Funder Grant number EPSRC EP/L017393/1 BBSRC (BIOTECHNOLOGY AND BIOLOGICAL SCIENCES RESEARCH COUNCIL) BB/N023595/1 |
Depositing User: | Pure (York) |
Date Deposited: | 21 Jan 2019 11:30 |
Last Modified: | 21 Nov 2024 00:38 |
Published Version: | https://doi.org/10.1039/C8PY01655K |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1039/C8PY01655K |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:141389 |
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