Tostevin, R, He, T orcid.org/0000-0001-8975-8667, Turchyn, AV et al. (5 more authors) (2017) Constraints on the late Ediacaran sulfur cycle from carbonate associated sulfate. Precambrian Research, 290. pp. 113-125. ISSN 0301-9268
Abstract
We report new sulfur isotope compositions (δ³⁴S) in carbonate associated sulfate (CAS) and pyrite from the lower Nama Group, Namibia (∼550 to <547 Ma), and use these data to interrogate terminal Ediacaran sulfur cycle dynamics. Our extraction method utilizes an improved pre-leaching procedure that reduces the likelihood of contamination from matrix-bound sulfur. Data generated with the improved extraction method show CAS δ³⁴S as much as 12‰ higher (³⁴SS-enriched) than previously reported which suggests a reevaluation of the phenomenon of ‘superheavy’ pyrite. The average δ³⁴S of seawater sulfate increases from 30 to 38‰ in the lower Nama Group, and we correlate this rise in δ³⁴S among contemporaneous marine basins. Global seawater sulfate δ³⁴S >35‰ is highly unusual in Earth history, and in the terminal Ediacaran is best explained by a high pyrite burial flux. Pyrite in the Nama Group is close in isotopic composition to coeval sulfate, but the sulfur isotope fractionation between sulfate and pyrite varies widely among different studied basins, suggesting highly heterogeneous redox and depositional conditions.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Keywords: | Sulfur isotopes; Neoproterozoic; Ediacaran; Superheavy pyrite; Method development; Carbonate-associated sulfate |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Earth and Environment (Leeds) > Earth Surface Science Institute (ESSI) (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 09 Aug 2018 13:22 |
Last Modified: | 03 Mar 2020 10:38 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.precamres.2017.01.004 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:134350 |