James, Michael J. orcid.org/0000-0003-2591-0046, O'Brien, Peter orcid.org/0000-0002-9966-1962, Taylor, Richard J K orcid.org/0000-0002-5880-2490 et al. (1 more author) (2016) Selective Synthesis of Six Products from a Single Indolyl α-Diazocarbonyl Precursor. Angewandte Chemie International Edition. pp. 9671-9675. ISSN 1433-7851
Abstract
Indolyl α-diazocarbonyls can be selectively cyclized to give six distinct products through the careful choice of catalyst and reaction conditions. A range of catalysts were used, including complexes of Rh(II) , Pd(II) , and Cu(II) , as well as SiO2 , to promote diazo decomposition and subsequent cyclization/rearrangement through a range of mechanistic pathways.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 Wiley-VCH Verlag GmbH & Co. K. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. Embargo period : 12 months |
Keywords: | cyclizations,diazo compounds,indoles,spirocycles,synthetic methods |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 25 Jul 2016 16:00 |
Last Modified: | 22 Mar 2025 00:06 |
Published Version: | https://doi.org/10.1002/anie.201605337 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201605337 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:102907 |
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Filename: Diazo_Diversity_version_7_shortened_AAM.docx
Description: Diazo Diversity version 7 shortened AAM