Xu, N. orcid.org/0000-0002-8291-6519, Wang, C. orcid.org/0000-0002-4301-3974, Wang, D. et al. (2 more authors) (Cover date: April 2024) Coating sensing strategy for understanding the governing factors of tribofilm growth on diamond-like carbon. Tribology International, 192. 109335. ISSN 0301-679X
Abstract
Tribofilms formed on coating surface can replace the original surface materials and dominate the final tribological behaviors. In-situ identification techniques of additive-derived tribofilm significantly contribute to understanding the tribo-chemical reaction mechanisms between additives and coatings. Here, a Raman-based profilometry was employed for in-situ identifying tribo-chemical products formed on a-C:H surface based on their distinct optical properties. By combining diverse characterization techniques, the effectiveness of Raman-based method was verified, and a surface-dependent tribofilm growth mechanism was proposed. It is suggested that the tribo-chemical reaction between additive-derived tribo-products and a-C:H is mainly governed by the Lewis acid-base property of coating surface under low contact pressure and temperature condition, highlighting the critical role of chemical property of coating surface in initiating tribofilm growth.
Metadata
Item Type: | Article | ||||||
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Copyright, Publisher and Additional Information: | © 2024 The Authors. This is an open access article under the terms of the Creative Commons Attribution License (CC-BY 4.0), which permits unrestricted use, distribution and reproduction in any medium, provided the original work is properly cited. | ||||||
Keywords: | Tribo-chemistry, Tribofilm growth, Additive, Raman, Diamond-like carbon, in-situ identification | ||||||
Dates: |
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Institution: | The University of Leeds | ||||||
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) > Institute of Functional Surfaces (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Mechanical Engineering (Leeds) > Institute of Engineering Thermofluids, Surfaces & Interfaces (iETSI) (Leeds) |
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Funding Information: |
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Depositing User: | Symplectic Publications | ||||||
Date Deposited: | 05 Mar 2024 10:57 | ||||||
Last Modified: | 05 Mar 2024 10:57 | ||||||
Status: | Published | ||||||
Publisher: | Elsevier | ||||||
Identification Number: | https://doi.org/10.1016/j.triboint.2024.109335 |