Greatorex, S, Fokin, SV, Kulmaczewski, R et al. (7 more authors) (2020) Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn–Teller Distortion. Inorganic Chemistry, 59 (13). pp. 8657-8662. ISSN 0020-1669
Abstract
A series of six-coordinate [Cu(L)L1][BF4]2 (L1 = 2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) complexes are reported. Ferromagnetic coupling between the Cu and L1 ligand spins is enhanced by an L coligand with distal methyl substituents, which is attributed to a sterically induced suppression of its Jahn–Teller distortion.
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Copyright, Publisher and Additional Information: | © 2020 American Chemical Society. This is an author produced version of an article published in Inorganic Chemistry. Uploaded in accordance with the publisher's self-archiving policy. | ||||||
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Institution: | The University of Leeds | ||||||
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) | ||||||
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Depositing User: | Symplectic Publications | ||||||
Date Deposited: | 08 Jun 2020 12:09 | ||||||
Last Modified: | 11 Jun 2021 00:38 | ||||||
Status: | Published | ||||||
Publisher: | American Chemical Society | ||||||
Identification Number: | https://doi.org/10.1021/acs.inorgchem.0c01345 | ||||||
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