Azpeitia, S, Martínez-Martínez, A J, Garralda, M A et al. (2 more authors) (2020) Si-C(sp3) bond activation through oxidative addition at a Rh(i) centre. Dalton Transactions. ISSN 1477-9234
Abstract
An easy, direct and room temperature silicon-carbon bond activation is reported. The reaction of [RhCl(coe)2]2 with the silane Si(Me)2(o-C6H4SMe)2 in the presence of an halide extractor provokes a Si-CH3 bond cleavage yielding a cationic silyl-methyl-Rh(iii). In contrast, if the reaction is performed using the Rh(i) bis-alkene dimers, [RhCl(cod)]2 or [RhCl(nbd)]2, the Si-CH3 bond activation does not occur.
Metadata
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2020. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. | ||||
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Institution: | The University of York | ||||
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) | ||||
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Depositing User: | Pure (York) | ||||
Date Deposited: | 03 Apr 2020 14:00 | ||||
Last Modified: | 06 Dec 2023 13:37 | ||||
Published Version: | https://doi.org/10.1039/D0DT00725K | ||||
Status: | Published | ||||
Refereed: | Yes | ||||
Identification Number: | https://doi.org/10.1039/D0DT00725K |