Cavallo, Gabriella, Terraneo, Giancarlo, Monfredini, Alessandro et al. (6 more authors) (2016) Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen-Bonded Anions. Angewandte Chemie International Edition. pp. 6300-6304. ISSN 1433-7851
Abstract
Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen-bonded supramolecular anions [CnF2n+1-I···I···I-CnF2n+1]- are reported. The material system is unique in many ways, demonstrating for the first time 1)ionic, halogen-bonded liquid crystals, and 2)imidazolium-based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. |
Keywords: | Fluorophobic effect,Halogen bonding,Ionic liquid crystals,Self-assembly,Supramolecular chemistry |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 05 May 2016 14:02 |
Last Modified: | 16 Oct 2024 12:59 |
Published Version: | https://doi.org/10.1002/anie.201601278 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201601278 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:99349 |