Holmes, J, Pask, CM, Fox, MA et al. (1 more author) (2016) Tethered N-Heterocyclic Carbene-Carboranes: Unique Ligands that Exhibit Unprecedented and Versatile Coordination Modes at Rhodium. Chemical Communications, 52 (38). pp. 6443-6446. ISSN 1359-7345
Abstract
Four brand new hybrid ligands combining an N-heterocyclic carbene tethered with two isomeric nido-dicarbaundecaborane dianions, a neutral closo-dicarbadodecaborane or a closo-dicarbadodecaborane anion are described. Versatile coordination of the ligands to RhI is demonstrated, in which both NHC and carborane moieties covalently coordinate a metal centre.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016, The Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 06 May 2016 14:12 |
Last Modified: | 14 Apr 2017 03:48 |
Published Version: | http://dx.doi.org/10.1039/C6CC01650B |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C6CC01650B |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:98345 |