Masters, Sarah L., Robertson, Heather E., Wann, Derek A. orcid.org/0000-0002-5495-274X et al. (5 more authors) (2015) Molecular structure of 1,2-bis(trifluoromethyl)-1,1,2,2-tetramethyldisilane in the gas, liquid, and solid phases:Unusual conformational changes between phases. Journal of Physical Chemistry A. pp. 1600-1608. ISSN 1089-5639
Abstract
The molecular structure of 1,2-bis(trifluoromethyl)-1,1,2,2-tetramethyldisilane has been determined in three different phases (solid, liquid, and gas) using various spectroscopic and diffraction techniques. Both the solid-state and gas-phase investigations revealed only one conformer to be present in the sample analyzed, whereas the liquid phase revealed the presence of three conformers. The data have been reproduced using computational methods and a rationale is presented for the observation of three conformers in the liquid state.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014 American Chemical Society. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) The University of York |
Funding Information: | Funder Grant number EPSRC EP/I004122/2 |
Depositing User: | Pure (York) |
Date Deposited: | 03 Feb 2016 17:43 |
Last Modified: | 21 Jan 2025 17:17 |
Published Version: | https://doi.org/10.1021/jp507744u |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1021/jp507744u |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:93798 |