Yildirir, E, Onwudili, JA and Williams, PT (2015) Chemical Recycling of Printed Circuit Board Waste by Depolymerization in Sub- and Supercritical Solvents. Waste and Biomass Valorization, 6 (6). 959 - 965. ISSN 1877-2641
Abstract
Disposal of waste printed circuit boards is regarded as a potential major environmental problem due to their heavy metal content. Therefore, recycling waste printed circuit boards represents an opportunity to recover the high value resin chemicals and the high value metals that are present. In this study, the solvo-thermal depolymerisation of waste printed circuit boards obtained from desktop computer monitors was carried out using water, ethanol and acetone between 300 and 400 °C. Alkalis (NaOH, KOH) were used as additives to promote the removal of the resin fraction of the printed circuit boards. At 400 °C, 94 % resin removal was achieved when water was used as the solvent, in the presence of NaOH. The liquid produced in the process was analysed by GC/MS and the results showed that it was mainly composed of phenol, and some phenolic compounds, with up to 62.5 wt% present as phenol in the liquid phase.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2015, Springer. This is an author produced version of a paper published in Waste and Biomass Valorization. Uploaded in accordance with the publisher's self-archiving policy. The final publication is available at Springer via http://dx.doi.org/10.1007/s12649-015-9426-8. |
Keywords: | Recycling; Supercritical; Depolymerisation; Printed circuit board |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) > Energy Research Institute (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 06 Jan 2016 09:42 |
Last Modified: | 16 Nov 2016 09:28 |
Published Version: | http://dx.doi.org/10.1007/s12649-015-9426-8 |
Status: | Published |
Publisher: | Springer Netherlands |
Identification Number: | 10.1007/s12649-015-9426-8 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:92487 |