Doyle, CM, Cunniffe, JP, Krasnikov, SA et al. (5 more authors) (2014) Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111). Chemical Communications, 50. 3447 - 3449. ISSN 1359-7345
Abstract
A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions that occur when the molecules are deposited on the Cu(111) surface.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Keywords: | Copper; Kinetics; Nickel; Porphyrins; Spectrum Analysis |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Colour Science (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 09 Oct 2015 12:39 |
Last Modified: | 04 Dec 2015 20:42 |
Published Version: | http://dx.doi.org/10.1039/c3cc48913b |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/c3cc48913b |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:87703 |
Download not available
A full text copy of this item is not currently available from White Rose Research Online