Lewis, TR orcid.org/0000-0001-6710-4021, Blitz, MA, Heard, DE orcid.org/0000-0002-0357-6238 et al. (1 more author) (2015) Direct evidence for a substantive reaction between the Criegee intermediate, CH₂OO, and the water vapour dimer. Physical Chemistry Chemical Physics, 17 (7). pp. 4859-4863. ISSN 1463-9076
Abstract
The C1 Criegee intermediate, CH2OO, reaction with water vapour has been studied. The removal rate constant shows a quadratic dependence on [H2O], implying reaction with the water dimer, (H2O)2. The rate constant, kCH2OO+(H2O)2 = (4.0 ± 1.2) × 10−12 cm3 molecule−1 s−1, is such that this is the major atmospheric sink for CH2OO.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Physical Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 02 Jul 2015 14:41 |
Last Modified: | 03 Jul 2019 16:36 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/c4cp04750h |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:85038 |