Brazier, JB, Nguyen, BN, Adrio, LA et al. (6 more authors) (2014) Catalysis in flow: Operando study of Pd catalyst speciation and leaching. Catalysis Today, 229. 95 - 103. ISSN 0920-5861
Abstract
A custom-made plug flow reactor was designed and constructed to examine the behaviour of Pd catalysts during Suzuki-Miyaura cross-coupling reactions. Spatial-temporal resolution of catalyst activation, deactivation and leaching processes can be obtained by single-pass experiments. Subsequent deployment of the flow reactor in a XAS beam line revealed speciation of Pd along the catalyst bed.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014. Elsevier. Uploaded in accordance with the publisher's self-archiving policy. NOTICE: this is the author’s version of a work that was accepted for publication in Catalysis Today. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Catalysis Today, 229,(2014) DOI:10.1016/j.cattod.2013.10.079 |
Keywords: | Suzuki-Miyaura reaction; Plug flow reactor; XAS; Catalyst deactivation; Leaching |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 23 Apr 2015 15:45 |
Last Modified: | 30 Jun 2020 14:50 |
Published Version: | http://dx.doi.org/10.1016/j.cattod.2013.10.079 |
Status: | Published |
Publisher: | Elsevier |
Refereed: | Yes |
Identification Number: | 10.1016/j.cattod.2013.10.079 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:84124 |