Chapman, MR, Pask, CM, Ariafard, A et al. (1 more author) (2015) σ-Alkenyl endo-palladacycle formation via regiospecific functionalisation of an unreactive NHC-tethered C(sp2)-H bond. Chemical Communications, 51 (25). 5513 - 5515. ISSN 1359-7345
Abstract
An unusual cyclometallation reaction at palladium is described, which proceeds via C-H functionalisation of a vinylic C(sp2)-H bond tethered to an NHC ligand. The energetic balance between palladacycle formation and bis-NHC complexation has been found to be very subtle.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | © 2015, Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self-archiving policy. |
| Dates: |
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| Institution: | The University of Leeds |
| Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) |
| Depositing User: | Symplectic Publications |
| Date Deposited: | 21 Apr 2015 12:06 |
| Last Modified: | 30 Jun 2020 14:50 |
| Published Version: | http://dx.doi.org/10.1039/c4cc10163d |
| Status: | Published |
| Publisher: | Royal Society of Chemistry |
| Refereed: | Yes |
| Identification Number: | 10.1039/c4cc10163d |
| Related URLs: | |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:84072 |
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