Dressel, C., Liu, F., Prehm, M. et al. (3 more authors) (2014) Dynamic Mirror-Symmetry Breaking in Bicontinuous Cubic Phases. Angewandte Chemie International Edition, 53 (48). 13115 - 13120. ISSN 1433-7851
Abstract
Chiral segregation of enantiomers or chiral conformers of achiral molecules during self-assembly in well-ordered crystalline superstructures has fascinated chemists since Pasteur. Here we report spontaneous mirror-symmetry breaking in cubic phases formed by achiral multichain-terminated diphenyl-2,2′-bithiophenes. It was found that stochastic symmetry breaking is a general phenomenon observed in bicontinuous cubic liquid crystal phases of achiral rod-like compounds. In all compounds studied the equation image cubic phase is always chiral, while the equation image phase is achiral. These intriguing observations are explained by propagation of homochiral helical twist across the entire networks through helix matching at network junctions. In the equation image phase the opposing chiralities of the two networks cancel, but not so in the three-networks equation image phase. The high twist in the equation image phase explains its previously unrecognized chirality, as well as the origin of this complex structure and the transitions between the different cubic phases.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Keywords: | chiral isotropic liquid; conglomerate; deracemization; polycatenar liquid crystal; spontaneous chiral induction |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number EPSRC EP-K034308-1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 03 Mar 2015 10:32 |
Last Modified: | 03 Mar 2015 10:32 |
Published Version: | http://dx.doi.org/10.1002/anie.201406907 |
Status: | Published |
Publisher: | John Wiley & Sons |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201406907 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:83932 |