Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand
Barrett, SA and Halcrow, MA
(2014)
Anion-dependent spin crossover in solution for an iron(ii) complex of a 1H-pyrazolyl ligand.
RSC Advances, 4 (22).
11240 - 11243.
Abstract
The spin-crossover equilibrium midpoint temperature (T1/2) in [Fe(3-bpp)2]X2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) varies from 259 K when X- = BPh4- to 277 K when X- = Br-, at 10 mM concentrations in an acetone-water solvent mixture.
Metadata
Item Type:
Article
Authors/Creators:
Barrett, SA
Halcrow, MA
Copyright, Publisher and Additional Information:
(c) 2014, Royal Society of Chemistry. This is an author produced version of a paper published in RSC Advances. Uploaded in accordance with the publisher's self-archiving policy.
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