Yao, D, Wu, C, Yang, H et al. (4 more authors) (2014) Hydrogen production from catalytic reforming of the aqueous fraction of pyrolysis bio-oil with modified Ni-Al catalysts. International Journal of Hydrogen Energy, 39 (27). 14642 - 14652. ISSN 0360-3199
Abstract
Hydrogen production from renewable resources has received extensive attention recently for a sustainable and renewable future. In this study, hydrogen was produced from catalytic steam reforming of the aqueous fraction of crude bio-oil, which was obtained from pyrolysis of biomass. Five Ni-Al catalysts modified with Ca, Ce, Mg, Mn and Zn were investigated using a fixed-bed reactor. Optimized process conditions were obtained with a steam reforming temperature of 800 °C and a steam to carbon ratio of 3.54. The life time of the catalysts in terms of stability of hydrogen production and prohibition of coke formation on the surface of the catalyst were carried out with continuous feeding of raw materials for 4 h. The results showed that the Ni-Mg-Al catalyst exhibited the highest stability of hydrogen production (56.46%) among the studied catalysts. In addition, the life-time test of catalytic experiments showed that all the catalysts suffered deactivation at the beginning of the experiment (reduction of hydrogen production), except for the Ni-Mg-Al catalyst; it is suggested that the observation of abundant amorphous carbon formed on the surface of reacted catalysts (temperature programmed oxidation results) may be responsible for the initial reduction of hydrogen production. In addition, the Ni-Ca-Al catalyst showed the lowest hydrogen production (46.58%) at both the early and stabilized stage of catalytic steam reforming of bio-oil.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | (c) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. Uploaded in accordance with the publisher's self-archiving policy. NOTICE: this is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, 39, 4, (2014) DOI 10.1016/j.ijhydene.2014.07.077 |
Keywords: | Bio-oil; Hydrogen; Ni-Al catalyst; Steam reforming |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) > Energy Research Institute (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 02 Oct 2014 10:45 |
Last Modified: | 16 Jan 2018 08:09 |
Published Version: | http://dx.doi.org/10.1016/j.ijhydene.2014.07.077 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.ijhydene.2014.07.077 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:80723 |