Metherell, A.J. and Ward, M.D. (2014) Stepwise synthesis of a Ru4Cd4 coordination cage using inert and labile subcomponents: introduction of redox activity at specific sites. Chemical Communications, 50. pp. 6330-6332.
Abstract
The kinetically inert mononuclear complex [RuL3](PF6)2 (1 : 3 mixture of fac and mer isomers), with three pendant binding sites, reacts with labile Cd(ii) ions to complete the assembly of a Ru4Cd4 cubic coordination cage in which reversible redox behaviour has been introduced at the Ru(ii) sites.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 20 Jun 2014 14:46 |
Last Modified: | 20 Jun 2014 14:46 |
Published Version: | http://dx.doi.org/10.1039/c4cc02627f |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Refereed: | Yes |
Identification Number: | 10.1039/c4cc02627f |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:79469 |