Metherell, A.J. and Ward, M.D. (2013) A tetrameric hetero-octanuclear cyclic helicate formed from a bridging ligand with two inequivalent binding sites. RSC Advances, 3 (34). 14281 - 14285. ISSN 2046-2069
Abstract
A bis-bidentate bridging ligand H2L with inequivalent hard and soft binding sites (catecholate and pyrazolyl-pyridine, respectively) reacts with a mixture of Ti(IV) and Zn(II) ions to afford an octanuclear heterometallic Ti4Zn4 cyclic helicate formed from four dinuclear {TiZn(m-L)2} units connected in a ring via methoxide ions.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2013 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 20 Jun 2014 14:11 |
Last Modified: | 20 Jun 2014 14:11 |
Published Version: | http://dx.doi.org/10.1039/c3ra42598c |
Status: | Published |
Publisher: | RSC Publishing |
Refereed: | Yes |
Identification Number: | 10.1039/c3ra42598c |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:79466 |