Supasitmongkol, S. and Styring, P. (2014) A single centre aluminium(III) catalyst and TBAB as an ionic organo-catalyst for the homogeneous catalytic synthesis of styrene carbonate. Catalysis Science and Technology, 4 (6). 1622 - 1630. ISSN 2044-4753
Abstract
A non-symmetrical aluminium complex containing a single metal centre has been synthesised and used as a catalyst in the cycloaddition reaction of carbon dioxide to styrene oxide to yield a cyclic carbonate. The reaction proceeds to around 70% conversion using the catalyst alone; however, it can be increased to 90% conversion with the addition of tetrabutylammonium bromide (TBAB) as a co-catalyst. Interestingly, the reaction proceeds as well with the organo-catalyst TBAB alone as it does with the aluminium catalyst alone. This offers the potential for reduced cost processing and scale-up of the reaction through elimination of the aluminium catalyst due to reduced catalyst costs and ease of separation of TBAB as a salt from the reaction mixture. The rate constants for the aluminium catalysed reactions were determined as a function of process temperature in the range 80–150 °C, as well as the activation energies for the reactions determined from the Arrhenius plots. The activation energy for the aluminium catalyst alone was determined to be 34 kJ mol−1, while adding TBAB as a co-catalyst reduced the activation energy by 11 kJ mol−1.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2014 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Chemical and Biological Engineering (Sheffield) |
Funding Information: | Funder Grant number EPSRC EP/E010318/1 EPSRC EP/H035702/1 EPSRC EP/K007947/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 20 Jun 2014 13:47 |
Last Modified: | 18 Nov 2016 17:10 |
Published Version: | http://dx.doi.org/10.1039/c3cy01015e |
Status: | Published |
Publisher: | RSC Publishing |
Refereed: | Yes |
Identification Number: | 10.1039/c3cy01015e |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:79463 |