Ellis, A, Wallace, M and Twyman, L.J (2013) Exploiting dense shell/packing principles to invoke stereoselectivity in a reaction accelerated by a chiral dendrimer. Chemical Communications, 49 (73). 8063 - 8065. ISSN 1359-7345
Abstract
As dendrimers approach their dense shell or dense packed limit, a certain amount of conformational organization exists. Any substrate binding within the dendrimer’s external layerwill experience the same organizational effects. This paper describes how these effects can be exploited towards stereocontrol with respect to binding and reactivity.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2013 The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Dates: |
|
Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Mechanical Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 16 Jun 2014 15:11 |
Last Modified: | 16 Jun 2014 15:11 |
Published Version: | http://dx.doi.org/10.1039/c3cc43830a |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Refereed: | Yes |
Identification Number: | 10.1039/c3cc43830a |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:79393 |