Cockett, C.R. and Watkins, M.J. (2004) Hydrogenic Rydberg states of molecular van der Waals complexes: Resolved Rydberg spectroscopy of DABCO-N2. Physical Review Letters, 92 (4). 043001-1. ISSN 0031-9007
Abstract
The complementary threshold ionization techniques of MATI and ZEKE spectroscopy have been used to reveal well-resolved, long-lived (>10 μs) hydrogenic Rydberg series (50≤n≤98) in a van der Waals complex formed between a polyatomic molecule and a diatomic molecule for the first time. The series are observed within 50 cm-1 of the adiabatic ionization threshold as well as two core-excited thresholds corresponding to excitation of up to two quanta in the van der Waals vibrational mode.
Metadata
| Item Type: | Article |
|---|---|
| Authors/Creators: |
|
| Dates: |
|
| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 23 Feb 2009 14:48 |
| Last Modified: | 23 Feb 2009 14:48 |
| Published Version: | http://dx.doi.org/10.1103/PhysRevLett.92.043001 |
| Status: | Published |
| Publisher: | American Physical Society |
| Identification Number: | 10.1103/PhysRevLett.92.043001 |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:7259 |
CORE (COnnecting REpositories)
CORE (COnnecting REpositories)