Cockett, C.R. and Watkins, M.J. (2004) Hydrogenic Rydberg states of molecular van der Waals complexes: Resolved Rydberg spectroscopy of DABCO-N2. Physical Review Letters, 92 (4). 043001-1. ISSN 0031-9007
Abstract
The complementary threshold ionization techniques of MATI and ZEKE spectroscopy have been used to reveal well-resolved, long-lived (>10 μs) hydrogenic Rydberg series (50≤n≤98) in a van der Waals complex formed between a polyatomic molecule and a diatomic molecule for the first time. The series are observed within 50 cm-1 of the adiabatic ionization threshold as well as two core-excited thresholds corresponding to excitation of up to two quanta in the van der Waals vibrational mode.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | York RAE Import |
Date Deposited: | 23 Feb 2009 14:48 |
Last Modified: | 23 Feb 2009 14:48 |
Published Version: | http://dx.doi.org/10.1103/PhysRevLett.92.043001 |
Status: | Published |
Publisher: | American Physical Society |
Identification Number: | 10.1103/PhysRevLett.92.043001 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:7259 |