Cronin, L. and Walton, P.H. (2003) Synthesis and structure of [Zn(OMe)(L)]-[Zn(OH)(L)].2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl) acrylideneamino] cyclohexane: structural models of carbonic anhydrase and liver alcohol dehydrogenase. Chemical Communications, 13. pp. 1572-1573. ISSN 1359-7345
Abstract
Direct reaction of [Zn(OH)(L)]+, L =cis,cis-1,3,5-tris[(E,E)-3-(2-furyl)acrylideneamino]cyclohexane, with methanol gives a mixture of the starting material and [Zn(OMe)(L)]+; structural analysis of the complexes shows that they are models of reactive intermediates in the catalytic cycles of the zinc enzymes carbonic anhydrase and liver alcohol dehydrogenase.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Dates: |
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| Institution: | The University of York |
| Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
| Depositing User: | York RAE Import |
| Date Deposited: | 04 Sep 2009 15:19 |
| Last Modified: | 04 Sep 2009 15:19 |
| Published Version: | http://dx.doi.org/10.1039/b302895j |
| Status: | Published |
| Publisher: | Elsevier |
| Identification Number: | 10.1039/b302895j |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:5871 |
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