Fish, C., Green, M., Kilby, R.J. et al. (6 more authors) (2006) A new reaction pathway in organophosphorus chemistry: competing SN2- and AE'-pathways for nucleophilic attack at a phosphorus-cage compound. Angewandte Chemie International Edition, 45 (22). pp. 3628-3631. ISSN 1433-7851
Abstract
Competition: A combination of 31P NMR spectroscopic and calculational studies have shown that nucleophilic substitution in the phosphorus-carbon cage compound ClP3(CtBu)2 occurs through competing SN2- and AE-type reaction pathways (see scheme for model compound ClP3(CH)2). The AE mechanism results in the formation of a C2v-symmetric intermediate prior to release of the chloride ion.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | York RAE Import |
Date Deposited: | 21 Aug 2009 10:14 |
Last Modified: | 21 Aug 2009 10:14 |
Published Version: | http://dx.doi.org/10.1002/anie.200504546 |
Status: | Published |
Publisher: | John Wiley & Sons |
Identification Number: | 10.1002/anie.200504546 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:5494 |
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