Bould, J., McInnes, Y.M., Carr, M.J. et al. (1 more author) (2004) Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)(4)(O-2)Pt2B10H10]. ChemicalL Communications (21). pp. 2380-2381. ISSN 1359-7345
Abstract
[(PMe2Ph)(4)Pt2B10H10] 1 reversibly takes up atmospheric dioxygen to give the fluxional dioxygen-dimetallaborane complex [(PMe2Ph)(4)(O-2)Pt2B10H10] 2, which has Pt-Pt 2.7143(3), Pt-O 2.141(4) and 2.151(4) and O-O 1.434(6) Angstrom.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2008 Royal Society of Chemistry. This is an author produced version of a paper published in Chemical Communications. Uploaded in accordance with the publisher's self archiving policy. |
Keywords: | Dimetallaboranes; Metallaborane reaction chemistry; Cluster bridging ligands; Dioxygen-diplatinum complex, Borane clusters; NMR; X-ray diffraction analysis; Diplatinum complex of molecular dioxygen; Dioxygen, reversible uptake by a dimetal system |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) |
Depositing User: | Repository Administrator York |
Date Deposited: | 04 Jun 2008 08:27 |
Last Modified: | 16 Sep 2016 13:36 |
Published Version: | http://dx.doi.org/10.1039/b406974a |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Refereed: | Yes |
Identification Number: | 10.1039/b406974a |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:3935 |