Shea, S.L., Jelínek, T., Perera, S.D. et al. (3 more authors) (2004) Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(eta(5)-C5Me5)HIrB18H19(PHPh2)] and [(eta(5) -C5Me5)IrB18H18(PH2Ph)]. Inorganica Chimica Acta, 357 (10). pp. 3119-3123. ISSN 0020-1693
Abstract
Fused double-cluster [(5-C5Me5)IrB18H18(PH2Ph)]8, from syn-[(5-C5Me5)IrB18H20] 1 and PH2Ph, retains the three-atoms-in-common cluster fusion intimacy of 1, in contrast to [(5-C5Me5)HIrB18H19(PHPh2)]6, from PHPh2 with 1, which exhibits an opening to a two atoms-in-common cluster fusion intimacy. Compound 8 forms via spontaneous dihydrogen loss from its precursor [(5-C5Me5)HIrB18H19(PH2Ph)]7, which has two-atoms-in-common cluster-fusion intimacy and is structurally analogous to 6.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2004 Elsevier Ltd. This is an author produced version of a paper published in Inorganica Chimica Acta. Uploaded in accordance with the publisher's self archiving policy. |
Keywords: | Borane cluster, Macropolyhedral opening and closure, X-ray structure, NMR spectroscopy, Redox changes in intercluster intimacy, Metallaborane, Iridium-borane cluster compound. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) |
Depositing User: | Repository Administrator York |
Date Deposited: | 22 Apr 2008 17:40 |
Last Modified: | 16 Sep 2016 13:35 |
Published Version: | http://dx.doi.org/10.1016/j.ica.2004.03.041 |
Status: | Published |
Publisher: | Elsevier Science B.V., Amsterdam |
Refereed: | Yes |
Identification Number: | 10.1016/j.ica.2004.03.041 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:3752 |