Berisha, A.P., Mykhaylyk, O.O. orcid.org/0000-0003-4110-8328, Armes, S.P. orcid.org/0000-0002-8289-6351 et al. (2 more authors) (2025) Determination of both wet and dry mass of water-soluble polymers adsorbed on planar silica using a quartz crystal microbalance. Langmuir. ISSN 0743-7463
Abstract
It is well-established that polymer adsorption at a model planar interface can be studied using a quartz crystal microbalance (QCM). Normally, this technique reports both the adsorbed mass of polymer chains plus any bound or entrained solvent molecules. Thus the total adsorbed amount significantly exceeds that reported by optical reflectometry or determined from adsorption isotherms obtained for colloidal substrates using a supernatant depletion assay. Herein we report a new QCM approach whereby the dry adsorbed amount, Γdry, is obtained directly from the wet (solvated) adsorbed amount, Γwet, by switching from a liquid flow to a flow of nitrogen gas. The latter conditions lead to complete removal of the solvent, leaving only the desolvated adsorbed polymer chains. This strategy is exemplified for the adsorption of two well-known nonionic water-soluble polymers, poly(ethylene glycol) (PEG) and poly(N-vinylpyrrolidone) (PNVP), from aqueous solution onto a model planar substrate (silica). These two systems were selected to facilitate direct comparison with the literature, which validates this new approach.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2025 The Authors. Except as otherwise noted, this author-accepted version of a journal article published in Langmuir is made available via the University of Sheffield Research Publications and Copyright Policy under the terms of the Creative Commons Attribution 4.0 International License (CC-BY 4.0), which permits unrestricted use, distribution and reproduction in any medium, provided the original work is properly cited. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ |
Keywords: | Adsorption; Nanoparticles; Polymers; Sensors; Silica |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > School of Mathematical and Physical Sciences |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 01 Jul 2025 15:14 |
Last Modified: | 01 Jul 2025 15:14 |
Status: | Published online |
Publisher: | American Chemical Society (ACS) |
Refereed: | Yes |
Identification Number: | 10.1021/acs.langmuir.5c01380 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:228602 |
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