Inthalaeng, Natthamon, Barker, Ryan E., Dugmore, Tom I.J. et al. (1 more author) (2024) Microwave-Assisted Production of Defibrillated Lignocelluloses from Blackcurrant Pomace via Citric Acid and Acid-Free Conditions. MOLECULES. 5665. ISSN 1420-3049
Abstract
Blackcurrant pomace (BCP) is an example of an annual, high-volume, under-utilized renewable resource with potential to generate chemicals, materials and bioenergy within the context of a zero-waste biorefinery. Herein, the microwave-assisted isolation, characterization and potential application of defibrillated lignocelluloses from depectinated blackcurrant pomace are reported. Depectination was achieved using citric acid (0.2–0.8 M, 80 °C, 2 h, conventional heating) and compared with acid-free hydrothermal microwave-assisted processing (1500 W, 100–160 °C, 30 min). The resultant depectinated residues were subjected to microwave-assisted hydrothermal defibrillation to afford two classes of materials: namely, (i) hydrothermal acid-free microwave-assisted (1500 W, 160 °C, 30 min; DFC-M1-M4), and (ii) hydrothermal citric acid microwave-assisted (1500 W, 160 °C, 30 min; DFC-C1–C4). Thermogravimetric analysis (TGA) revealed that the thermal stability with respect to native BCP (Td = 330 °C) was higher for DFC-M1-M4 (Td = 345–348 °C) and lower for DFC-C1–C4 (322–325 °C). Both classes of material showed good propensity to hold water but failed to form stable hydrogels (5–7.5 wt% in water) unless they underwent bleaching which removed residual lignin and hemicellulosic matter, as evidenced by 13C solid-state NMR spectroscopy. The hydrogels made from bleached DFC-C1–C4 (7.5 wt%) and bleached DFC-M1-M4 (5 wt%) exhibited rheological viscoelastic, shear thinning, and time-dependent behaviour, which highlights the potential opportunity afforded by microwave-assisted defibrillation of BCP for food applications.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | Publisher Copyright: © 2024 by the authors. |
Keywords: | biomass pretreatment,biomass waste,blackcurrant pomace,citric acid pretreatment,defibrillated (ligno)cellulose,microwave hydrothermal treatment |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 02 Jan 2025 12:40 |
Last Modified: | 02 Jan 2025 12:40 |
Published Version: | https://doi.org/10.3390/molecules29235665 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.3390/molecules29235665 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:221200 |
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Description: Microwave-Assisted Production of Defibrillated Lignocelluloses from Blackcurrant Pomace via Citric Acid and Acid-Free Conditions
Licence: CC-BY 2.5