Revealing the Hidden Complexity and Reactivity of Palladacyclic Precatalysts:The P(o-tolyl)3 Ligand Enables a Cocktail of Active Species Utilizing the Pd(II)/Pd(IV) and Pd(0)/Pd(II) Pathways for Efficient Catalysis

Husbands, David R., Tanner, Theo, Whitwood, Adrian C. et al. (3 more authors) (2024) Revealing the Hidden Complexity and Reactivity of Palladacyclic Precatalysts:The P(o-tolyl)3 Ligand Enables a Cocktail of Active Species Utilizing the Pd(II)/Pd(IV) and Pd(0)/Pd(II) Pathways for Efficient Catalysis. ACS Catalysis. pp. 12769-12782. ISSN 2155-5435

Abstract

Metadata

Item Type: Article
Authors/Creators:
Copyright, Publisher and Additional Information:

© 2024 The Authors. Published by American Chemical Society.

Keywords: cross-coupling,Heck,kinetics,mechanism,palladacycle,palladium,Suzuki−Miyaura
Dates:
  • Published: 9 August 2024
  • Accepted: 22 July 2024
Institution: The University of York
Academic Units: The University of York > Faculty of Sciences (York) > Chemistry (York)
Funding Information:
Funder
Grant number
EPSRC
EP/P011217/1
THE ROYAL SOCIETY
INF\R2\202122
Depositing User: Pure (York)
Date Deposited: 15 Oct 2024 08:40
Last Modified: 10 Feb 2025 00:11
Published Version: https://doi.org/10.1021/acscatal.4c02585
Status: Published
Refereed: Yes
Identification Number: 10.1021/acscatal.4c02585
Related URLs:
Open Archives Initiative ID (OAI ID):

Download

Filename: husbands-et-al-2024-revealing-the-hidden-complexity-and-reactivity-of-palladacyclic-precatalysts-the-p_o-tolyl_3-ligand.pdf

Description: husbands-et-al-2024-revealing-the-hidden-complexity-and-reactivity-of-palladacyclic-precatalysts-the-p(o-tolyl)3-ligand

Licence: CC-BY 2.5

Export

Statistics