Chhaiba, S., Martinez-Sanchez, S., Husillos-Rodriguez, N. et al. (3 more authors) (2024) Durability of magnesium potassium phosphate cements (MKPCs) under chemical attack. Materials, 17 (17). 4252. ISSN 1996-1944
Abstract
Magnesium phosphate cements (MPCs), also known as chemically bonded ceramics, represent a class of inorganic cements that have garnered considerable interest in recent years for their exceptional properties and diverse applications in the construction and engineering sectors. However, the development of these cements is relatively recent (they emerged at the beginning of the 20th century), so there are still certain aspects relating to their durability that need to be evaluated. The present work analyses the chemical durability of magnesium potassium phosphate cements (MKPCs) during 1 year of immersion in three leaching media: seawater, a Na2SO4 solution (4% by mass) and deionized water. For this, pastes of prismatic specimens of MKPC, prepared with different M/P ratio (2 and 3), were submitted to the different chemical attacks. At different ages, the changes on the mechanical strengths, microstructure (BSEM, MIP) and mineralogy (XRD, FTIR, TG/DTG) were evaluated. The results obtained indicate that, in general terms, MKPC systems show good behavior in the three media, with the more resistant system being the one prepared with a M/P molar ratio of 3.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
Keywords: | durability; magnesium potassium phosphate cements (MKPCs); K-struvite; low-grade MgO; chemical attack |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > School of Chemical, Materials and Biological Engineering The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 09 Sep 2024 14:50 |
Last Modified: | 09 Sep 2024 14:50 |
Status: | Published |
Publisher: | MDPI AG |
Refereed: | Yes |
Identification Number: | 10.3390/ma17174252 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:217001 |