Lakey, P., Berkemeier, T., Baeza-Romero, M.T.T. et al. (3 more authors) (2024) Towards a better understanding of the HO2 uptake coefficient to aerosol particles measured during laboratory experiments. Environmental Science: Atmospheres, 4 (7). pp. 813-829. ISSN 2634-3606
Abstract
The first measurements of HO2 uptake coefficients (γHO2) onto suspended aerosol particles as a function of temperature are reported in the range 314 K to 263 K. For deliquesced ammonium nitrate (AN) particles γHO2 increases from 0.005 ± 0.002 to 0.016 ± 0.005 as the temperature is lowered over this range. For effloresced sodium chloride and ammonium sulphate particles, γHO2 decreases slightly from 0.004 ± 0.002 to 0.000 ± 0.002 and 0.002 ± 0.003, respectively, between 314 and 263 K. For AN particles doped with Cu2+ ions, we find γHO2 ≈ αHO2, the mass accommodation coefficient, which increases very slightly from γHO2 = 0.62 ± 0.05 to 0.71 ± 0.06 between 292 and 263 K with lowering temperature. New measurements of γHO2 are also reported for ammonium sulphate particles doped with a range of Fe2+ and Fe3+ concentrations. The dependence of γHO2 on Cu and Fe concentrations are reconciled with published rate coefficients using the kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB). The model shows that in experimental studies using aerosol flow tubes, a time dependence is expected for γHO2 onto aerosol particles which do not contain transition metal ions due to a decrease in the gas-phase concentration of HO2 as a function of time. The model also demonstrates that Fenton-like chemistry has the potential to decrease γHO2 as a function of time for particles containing transition metal ions. For atmospherically relevant transition metal ion concentrations in aerosol particles, γHO2 can take a range of values depending on pH and the particle size from γHO2 < 0.04 to γHO2 = αHO2. γHO2 for larger particles (radius >= 0.5 μm) can be significantly reduced by gas-diffusion limitations.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2024 The Author(s). This is an open access article under the terms of the Creative Commons Attribution License (CC-BY 3.0). |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Physical Chemistry (Leeds) |
Funding Information: | Funder Grant number NERC (Natural Environment Research Council) NE/F020651/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 18 Jun 2024 14:55 |
Last Modified: | 30 Sep 2024 13:57 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/d4ea00025k |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:213563 |