Pramanik, D.D., Kay, P. and Goycoolea, F.M. (2024) A rapid and portable fluorescence spectroscopy staining method for the detection of plastic microfibers in water. Science of The Total Environment, 908. 168144. ISSN 0048-9697
Abstract
We propose a simple technique for microplastic detection based on their interaction with a hydrophilic and anionic fluorescent dye 1,3,6,8 pyrene tetrasulfonate (PTSA). Synthetic microfibers derived from surgical face masks (an abundantly generated plastic waste post COVID) were considered as model microplastics. The interactions between microfibers and the dye were studied as a function of physiological parameters (pH, contact time and temperature), external agents, dye dosage and polymer variants. A pocket-sized photometer (by Lovibond Tintometer group) was employed for the detection and further validated using advanced equipment set-ups (fluorescence microscope, Fourier transform infrared spectroscopy and benchtop spectrofluorometer). Risk assessment studies were conducted on Artemia salina as a model organism. As a risk mitigation strategy, dye recovery followed by sunlight mediated degradation were performed. The detection study was performed in real water samples collected from fresh, estuarine and seawater samples spiked with microfibers. As an outcome, an optimized standard operational conditions were determined for the effective detection of synthetic microfibers. The data obtained could have scientific and industrial impact, in particular for experts working in the broad arena of clean water, who are specifically interested in developing cost-effective solutions for effective detection and biomonitoring of emerging pollutants.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2023 The Authors. This is an open access article under the terms of the Creative Commons Attribution License (CC-BY-NC-ND 4.0), which permits unrestricted use, distribution and reproduction in any medium, provided the original work is properly cited. |
Keywords: | 1,3,6,8 Pyrene Tetrasulfonate (PTSA); Fluorescence-based detection; Microfibers; Portable photometer |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Food Science and Nutrition (Leeds) > FSN Chemistry and Biochemistry (Leeds) |
Funding Information: | Funder Grant number EU - European Union 897736 |
Depositing User: | Symplectic Publications |
Date Deposited: | 04 Jun 2024 11:33 |
Last Modified: | 04 Jun 2024 11:33 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.scitotenv.2023.168144 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:213036 |